I have never used BALANCE roll-on blends which ones best to start with?

It really depends on what you like, but we do have a few favourites ourselves:
Morning energy: this blend is perfect to start your day, it increase alertness naturally.
Focus: this blend makes your mind clear and increase mental clarity, it is fresh and uplifting.
Bye bye pain: this blend helps to reduce tension in any part of the body with pain, it is incredibly comforting.
Take a look at our blog, essential oils 101, for more inspiration.